Beilstein J. Nanotechnol.2020,11, 1217–1229, doi:10.3762/bjnano.11.106
pores is nontrivial, we herein employ Kr, N2 and CO2 gassorptionporosimetry, as well as H2O vapor sorption porosimetry, to investigate eight hard carbons. Electrochemical lithium as well as sodium storage tests are compared to the obtained apparent surface areas and pore volumes. H2O, and more
descriptors to the obtained capacities remains a scientific challenge.
Keywords: alkaline-ion secondary battery; gassorptionporosimetry; hard carbon; irreversible capacity; ultramicroporosity; Introduction
Lithium-ion battery (LIB)-based energy storage devices have been gaining high interest in the recent
]. These unwanted side reactions are expected to reduce the reversible capacity that can be obtained by adsorption within the pore system.
In this work, we use different gassorptionporosimetry (GSP) techniques to investigate surface areas and porosities, contributed by pores of different size, of
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Figure 1:
SEM images of HT carbons: a) HT1, b) HT2, c) HT3, d) HT4, e) HT5 and f) HT6.